Top 10 Companies in the HFO-1336mzz(Z) Market (2026): Market Leaders Driving Sustainable Refrigeration

MARKET INSIGHTS

Global HFO-1336mzz(Z) market was valued at USD 185 million in 2024 and is projected to reach USD 419 million by 2032, exhibiting a CAGR of 12.1% during the forecast period. The U.S. market accounted for a significant share in 2024, while China is expected to witness accelerated growth.

HFO-1336mzz(Z) is a fourth-generation hydrofluoroolefin (HFO) with the chemical name cis-1,1,1,4,4,4-hexafluoro-2-butene (CAS 692-49-9). It represents an environmentally friendly alternative to traditional refrigerants because it features zero ozone depletion potential (ODP) and an ultra‑low global warming potential (GWP) ranging between 2 and 9.4. These properties make it increasingly vital for applications in refrigeration, air conditioning, and foam blowing.

The market growth is driven by stringent environmental regulations phasing out high‑GWP refrigerants, particularly in North America and Europe. Furthermore, rising demand for energy‑efficient cooling systems in commercial and industrial sectors is expanding adoption. Key players such as Chemours, Honeywell, and Quanzhou Yuji dominate the market, with the top five companies holding a substantial revenue share in 2024. The purity ≥99% segment is anticipated to grow robustly, supported by its superior performance in precision applications.

HFO-1336mzz(Z) Market – View in Detailed Research Report

MARKET SIZE

The HFO-1336mzz(Z) market was valued at USD 185 million in 2024 and is projected to reach USD 419 million by 2032, growing at a CAGR of 12.1% during the forecast period.

PRODUCT DEFINITION

HFO-1336mzz(Z) is a non‑flammable, zero‑ODP refrigerant with an ultra‑low GWP, making it ideal for refrigeration, air conditioning, and foam blowing applications. Its high purity (≥99%) is critical for precision processes, while lower purity grades (<99%) are suitable for cost‑sensitive foam expansion.

Top 10 Companies in the HFO-1336mzz(Z) Market

🔟 1. Chemours Company

Headquarters: Wilmington, Delaware, USA
Key Offering: HFO-1336mzz(Z) refrigerant for HVAC and foam blowing

Chemours has been a pioneer in HFO technology, developing proprietary synthesis routes that reduce environmental impact and improve energy efficiency. The company’s global distribution network ensures timely supply across North America and Europe.

Sustainability Initiatives:

• Early‑mover advantage in low‑GWP refrigerant development
• Investment in carbon‑neutral production facilities
• Partnerships with HVAC OEMs for integrated system design

9️⃣ 2. Honeywell International Inc.

Headquarters: Charlotte, North Carolina, USA
Key Offering: HFO-1336mzz(Z) for commercial chillers and industrial refrigeration

Honeywell leverages its strong fluorochemical expertise to deliver high‑purity HFO solutions. Recent capacity expansions in Asia‑Pacific position the company to capture emerging market opportunities.

Sustainability Initiatives:

• Vertically integrated production for supply chain resilience
• Strategic alliances with HVAC equipment manufacturers
• Commitment to reducing lifecycle GHG emissions

8️⃣ 3. Quanzhou Yuji Advanced Materials

Headquarters: Quanzhou, China
Key Offering: HFO-1336mzz(Z) for foam blowing and refrigeration

Quanzhou Yuji has scaled production to meet both domestic demand and export markets. The company focuses on cost‑optimized manufacturing and localized distribution, making HFO solutions accessible across China.

Sustainability Initiatives:

• Government‑backed green manufacturing incentives
• Collaboration with Chinese HVAC OEMs for low‑GWP solutions
• Investment in research for higher purity grades

7️⃣ 4. Sinochem Group

Headquarters: Beijing, China
Key Offering: HFO-1336mzz(Z) for industrial refrigeration and foam blowing

Sinochem’s diversified portfolio includes advanced fluorochemicals. The group’s strategic partnerships with global OEMs enhance market penetration in both China and export markets.

Sustainability Initiatives:

• Integration of renewable energy in production plants
• Support for China’s Kigali Amendment commitments
• Development of high‑purity HFO formulations

6️⃣ 5. Daikin Industries, Ltd.

Headquarters: Osaka, Japan
Key Offering: HFO-1336mzz(Z) for commercial HVAC and residential air conditioning

Daikin’s expertise in HVAC technology allows it to incorporate HFO refrigerants into next‑generation chillers, delivering superior energy efficiency and compliance with European regulations.

Sustainability Initiatives:

• Zero‑GWP product line expansion
• Energy‑saving HVAC solutions for LEED‑certified buildings
• Investment in R&D for higher temperature applications

5️⃣ 6. Arkema S.A.

Headquarters: Paris, France
Key Offering: HFO-1336mzz(Z) for foam blowing and refrigeration

Arkema’s chemical innovation pipeline includes advanced fluorochemicals. The company partners with European manufacturers to provide high‑purity HFO solutions for circular economy initiatives.

Sustainability Initiatives:

• Carbon‑neutral production facilities in Europe
• Collaboration with EU F‑Gas regulation stakeholders
• Research on biodegradable foam additives

4️⃣ 7. Solvay S.A.

Headquarters: Brussels, Belgium
Key Offering: HFO-1336mzz(Z) for industrial refrigeration and foam blowing

Solvay’s global footprint and advanced process engineering enable efficient production of high‑purity HFO refrigerants, meeting stringent EU and US standards.

Sustainability Initiatives:

• Reduction of CO₂ emissions in manufacturing
• Partnerships with automotive OEMs for low‑GWP cooling
• Investment in circular economy projects

3️⃣ 8. Mexichem S.A.B. de C.V.

Headquarters: Mexico City, Mexico
Key Offering: HFO-1336mzz(Z) for refrigeration and foam blowing in Latin America

Mexichem’s regional distribution network supports the growing demand for sustainable refrigerants across North and South America, offering cost‑competitive solutions.

Sustainability Initiatives:

• Expansion of low‑GWP product portfolio
• Collaboration with local governments on green infrastructure
• Investment in renewable energy for production sites

2️⃣ 9. Air Liquide

Headquarters: Paris, France
Key Offering: HFO-1336mzz(Z) for industrial refrigeration and specialty chemical processes

Air Liquide’s expertise in gases and chemicals positions it to supply high‑purity HFO solutions for precision applications in electronics and semiconductor manufacturing.

Sustainability Initiatives:

• Zero‑emission production lines
• Partnerships with semiconductor fabs for cleanroom cooling
• Development of energy‑efficient refrigeration systems

1️⃣ 10. Mitsubishi Chemical

Headquarters: Tokyo, Japan
Key Offering: HFO-1336mzz(Z) for HVAC, refrigeration, and foam blowing

Mitsubishi Chemical’s advanced fluorochemical technology enables the production of high‑purity HFO refrigerants, supporting global HVAC and refrigeration markets.

Sustainability Initiatives:

• Carbon‑neutral manufacturing facilities
• Collaboration with global HVAC OEMs for low‑GWP solutions
• Investment in R&D for higher temperature performance

Download FREE Sample Report

Get Full Report Here

OUTLOOK

Global HFO-1336mzz(Z) market is poised for robust growth, driven by regulatory momentum and the shift toward sustainable cooling solutions. Key trends include the expansion of high‑purity applications, increased adoption in semiconductor manufacturing, and strategic partnerships between chemical producers and HVAC OEMs.

FUTURE TRENDS

• Development of higher purity grades to meet precision demands
• Expansion into energy storage and battery thermal management
• Integration of HFO refrigerants in electric vehicle cooling systems
• Continued focus on reducing production costs through process innovation