The Global 1,1,1,4,4,4-Hexafluoro-2-Butene Market was valued at USD 310 Million in 2024 and is projected to reach USD 719 Million by 2032, growing at a Compound Annual Growth Rate (CAGR) of 12.6% during the forecast period (2024–2032). This growth is being driven by stringent environmental regulations, rising demand for low-GWP refrigerants in HVAC systems, and expanding applications as foaming agents in energy-efficient polyurethane insulation, particularly across industrial refrigeration, commercial cooling, and green construction sectors.

As the chemical industry shifts toward sustainable, low-global-warming-potential solutions amid global phase-downs of high-GWP HFCs, the focus turns to pioneering producers who are innovating production processes, scaling capacities, and enabling eco-friendly alternatives. In this blog, we profile the Top 10 Companies in the 1,1,1,4,4,4-Hexafluoro-2-Butene Industry—a blend of fluorochemical giants, specialty gas leaders, and regional innovators shaping the future of next-generation refrigerants and blowing agents.

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🔟 1. Zhejiang Sanmei Chemical Industry Co., Ltd.

Headquarters: Zhejiang, China
Key Offering: HFO-1336mzz(Z), HFO-1336mzz(E), Refrigerant Blends

Zhejiang Sanmei Chemical is a rising force in Asia’s fluorochemical sector, specializing in hydrofluoroolefins for refrigeration and foam applications. The company supplies HFO-1336mzz to domestic HVAC manufacturers and exports to emerging markets, leveraging cost-effective production to meet surging demand from China’s industrial expansion. Their facilities emphasize high-purity isomers for optimal performance in commercial chillers and insulation foams.

Innovation Initiatives:

• Advanced catalyst processes improving yield to over 85%
• Partnerships with appliance makers for low-GWP system integration
• Investments in capacity to support regional carbon neutrality goals

Download FREE Sample Report: 1,1,1,4,4,4-Hexafluoro-2-Butene Market – View in Detailed Research Report

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9️⃣ 2. Fluorochem Ltd.

Headquarters: Derbyshire, United Kingdom
Key Offering: HFO-1336mzz, Specialty Fluorocarbons, Custom Blends

Fluorochem Ltd. serves European markets with high-quality HFO-1336mzz for research and industrial use, focusing on polyurethane foaming agents compliant with F-Gas regulations. Operating from advanced labs, they provide tailored solutions for energy-efficient building materials and refrigeration retrofits, helping clients navigate the EU’s 70% HFC reduction by 2030.

Innovation Initiatives:

• R&D for compatible lubricants reducing retrofit costs
• Supply chain collaborations for seamless F-Gas compliance

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8️⃣ 3. Central Glass Co., Ltd.

Headquarters: Tokyo, Japan
Key Offering: HFO-1336mzz(E), Refrigerants, Foam Blowing Agents

Central Glass excels in precision fluorochemicals, supplying HFO-1336mzz to Japan’s high-tech refrigeration and electronics sectors. Their products support advanced cooling in data centers and appliances, with a focus on thermal stability and low environmental impact, aligning with national energy efficiency standards.

Innovation Initiatives:

• Developments in electronics cooling applications
• Targets for zero ODP foams in construction

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7️⃣ 4. Shandong Dongyue Chemical Co., Ltd.

Headquarters: Shandong, China
Key Offering: HFO-1336mzz(Z), Industrial Refrigerants, Blowing Agents

Shandong Dongyue is a major Chinese producer scaling HFO-1336mzz output to fuel the Asia-Pacific boom in air conditioning and insulation. Their integrated manufacturing reduces costs, enabling competitive pricing for large-scale polyurethane foam production in green buildings and appliances.

Innovation Initiatives:

• Energy-efficient synthesis cutting consumption by 30%
• Expansion plans for 14% CAGR in regional markets

Download FREE Sample Report: 1,1,1,4,4,4-Hexafluoro-2-Butene Market – View in Detailed Research Report

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6️⃣ 5. Sinochem Lantian Co., Ltd.

Headquarters: Henan, China
Key Offering: HFO-1336mzz, HFC Replacements, Foam Additives

Sinochem Lantian contributes to China’s refrigerant transition with reliable HFO-1336mzz supply for commercial and industrial uses. They emphasize stable isomer production, supporting Kigali Amendment compliance and growth in high-density insulation foams.

Innovation Initiatives:

• Compatibility testing for HVAC retrofits
• Sustainable manufacturing aligned with 2060 carbon goals

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5️⃣ 6. Quanzhou Yuji Advanced Materials Co., Ltd.

Headquarters: Fujian, China
Key Offering: HFO-1336mzz Blends, Low-GWP Refrigerants

Quanzhou Yuji leverages efficient processes to capture developing market share with affordable HFO-1336mzz, ideal for price-sensitive refrigeration. Their aggressive expansion addresses supply constraints, fueling 13% growth in the Z-isomer segment.

Innovation Initiatives:

• Cost reductions of 18% since 2020
• Strategic alliances for Asia-Pacific distribution

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4️⃣ 7. Air Liquide S.A.

Headquarters: Paris, France
Key Offering: HFO-1336mzz, Specialty Gases, Refrigerant Solutions

Air Liquide strengthens its fluorochemical portfolio with HFO-1336mzz for European and global clients, reporting strong sales growth. They focus on industrial refrigeration and foam blowing, with innovations in purity for high-performance applications.

Innovation Initiatives:

• Acquisitions boosting capacity
• 14% YoY fluorochemical growth

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3️⃣ 8. Honeywell International Inc.

Headquarters: Charlotte, North Carolina, USA
Key Offering: Genetron® HFO-1336mzz, Refrigerants, Foaming Agents

Honeywell competes aggressively with patented Genetron® products, dominating in Asia and North America. Their HFO-1336mzz supports HVAC transitions, with expansions targeting refrigerant phase-outs and superior foam insulation.

Innovation Initiatives:

• Multi-million capacity expansions
• System optimizations reducing conversion costs

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2️⃣ 9. The Chemours Company

Headquarters: Wilmington, Delaware, USA
Key Offering: Solstice® HFO-1336mzz, Low-GWP Refrigerants

Chemours leads with Solstice® HFO-1336mzz, holding major revenue share through robust networks. They drive adoption in North America and Europe, investing in production to meet regulatory demands and Z-isomer growth to USD 420 million by 2032.

Innovation Initiatives:

• Patented processes for ultra-low GWP
• Sustainability-focused expansions

Download FREE Sample Report: 1,1,1,4,4,4-Hexafluoro-2-Butene Market – View in Detailed Research Report

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1️⃣ 10. Arkema S.A.

Headquarters: Colombes, France
Key Offering: HFO-1336mzz, Advanced Refrigerants, Blowing Agents

Arkema tops the list as a global innovator in fluorinated specialties, supplying HFO-1336mzz for cutting-edge refrigeration and foams. With expertise in sustainable chemistry, they enable low-GWP transitions worldwide, partnering on electronics cooling and green construction.

Innovation Initiatives:

• Next-gen synthesis for scalability
• Collaborations for data center immersion cooling

Read Full Report: 1,1,1,4,4,4-Hexafluoro-2-Butene Market – View in Detailed Research Report

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🌍 Outlook: The Future of 1,1,1,4,4,4-Hexafluoro-2-Butene Is Greener and More Efficient

The 1,1,1,4,4,4-Hexafluoro-2-Butene market is experiencing rapid transformation. Traditional HFCs give way to this ultra-low GWP alternative, with billions invested in production expansions, process efficiencies, and application diversification from refrigeration to advanced foams.

📈 Key Trends Shaping the Market:

• Rapid capacity growth in Asia-Pacific, Europe, and North America
• Regulatory mandates for 2-10% low-GWP blending by 2030
• Digital supply chain tracking for compliance and emissions
• Industry partnerships accelerating HFO adoption

Read Full Report: 1,1,1,4,4,4-Hexafluoro-2-Butene Market – View in Detailed Research Report

The companies listed above are not only powering sustainable cooling—they’re leading the global shift to eco-friendly chemicals.