Top 10 Companies in the Corn-Based Ethanol Industry (2025): Market Leaders Fueling Global Biofuel Production

In Business Insights
November 23, 2025

The Global Corn-Based Ethanol Market was valued at USD 84.6 Billion in 2024 and is projected to reach USD 116.3 Billion by 2030, growing at a Compound Annual Growth Rate (CAGR) of 5.2% during the forecast period (2024–2030). This expansion is primarily driven by the global push for renewable energy, stringent environmental regulations, and the increasing adoption of ethanol-blended fuels to reduce greenhouse gas emissions from the transportation sector.

As nations worldwide intensify their efforts toward decarbonization and energy security, corn-based ethanol stands as a critical biofuel. Leading this charge are the key producers and technology innovators who are optimizing production efficiency and expanding capacity. In this blog, we profile the Top 10 Companies in the Corn-Based Ethanol Industry—agribusiness giants, pure-play producers, and integrated energy companies shaping the future of sustainable fuel.


🔟 1. Archer-Daniels-Midland Company (ADM)

Headquarters: Chicago, Illinois, USA
Key Offering: Fuel-Grade Ethanol, High-Purity Ethanol, Distillers Grains

ADM is a global leader in agricultural processing and a top producer of corn-based ethanol. With a vast network of dry and wet milling plants across the U.S. agricultural heartland, ADM is a cornerstone of the North American biofuel supply chain, providing fuel ethanol for blending and industrial-grade ethanol for various applications.

Sustainability & Innovation Initiatives:

  • Investment in carbon capture and storage (CCS) technologies at ethanol facilities

  • Development of next-generation biofuels and renewable chemicals

  • Commitment to sustainable agriculture sourcing for corn feedstock

Download FREE Sample Report: Corn-Based Ethanol Market – View in Detailed Research Report


9️⃣ 2. POET, LLC

Headquarters: Sioux Falls, South Dakota, USA
Key Offering: Biofuel (Ethanol), Distillers Grains, Corn Oil

POET is one of the world’s largest ethanol producers, operating numerous biorefining facilities primarily in the United States. Known for its proprietary BPX™ fermentation technology, which eliminates the need for heat in the cooking process, POET emphasizes efficiency and environmental stewardship in its operations.

Sustainability & Innovation Initiatives:

  • Pioneering low-carbon intensity ethanol production processes

  • Expansion of bioproducts portfolio beyond fuel, including renewable CO2

  • Active advocacy for year-round E15 fuel sales


8️⃣ 3. Valero Energy Corporation

Headquarters: San Antonio, Texas, USA
Key Offering: Fuel Ethanol, Distillers Grains, Corn Oil

Valero, a leading international petroleum refiner, is also one of the largest ethanol producers through its subsidiary, Valero Renewable Fuels. Its ethanol plants are strategically located near its refineries, creating an integrated energy production model that supports the supply of blended transportation fuels.

Sustainability & Innovation Initiatives:

  • Significant capital investments to increase plant efficiency and output

  • Focus on reducing the carbon footprint of its ethanol production lifecycle

  • Strategic alignment with national renewable volume obligations (RVOs)


7️⃣ 4. Green Plains Inc.

Headquarters: Omaha, Nebraska, USA
Key Offering: Ultra-High Protein, Fuel Ethanol, Corn Oil

Green Plains has transformed from a traditional ethanol producer into an innovative biorefining company. Its proprietary Ultra-High Protein (UHP) technology process increases the protein content of its co-products, adding significant value and creating sustainable animal feed ingredients.

Sustainability & Innovation Initiatives:

  • Deployment of UHP technology across its asset base

  • Partnerships focused on the production of sustainable aviation fuel (SAF) precursors

  • Commitment to achieving net-zero carbon emissions by 2050

Download FREE Sample Report: Corn-Based Ethanol Market – View in Detailed Research Report


6️⃣ 5. Flint Hills Resources, LP

Headquarters: Wichita, Kansas, USA
Key Offering: Fuel-Grade Ethanol, Distillers Grains

A subsidiary of Koch Industries, Flint Hills Resources is a major player in the ethanol and crude oil refining sectors. The company operates large-scale ethanol plants in the Midwest, leveraging its integrated logistics and marketing capabilities to serve fuel markets efficiently.

Sustainability & Innovation Initiatives:

  • Continuous optimization of energy and water usage in production facilities

  • Investment in pipeline and rail logistics for efficient fuel distribution

  • Focus on operational excellence and environmental compliance


5️⃣ 6. CHS Inc.

Headquarters: Inver Grove Heights, Minnesota, USA
Key Offering: Ethanol, Distillers Grains, Lubricants

CHS is a leading farmer-owned cooperative and a significant ethanol producer. Its business model is deeply integrated with the agricultural community, ensuring a reliable supply of corn feedstock while providing a vital market for member-owned grain.

Sustainability & Innovation Initiatives:

  • Strengthening the farmer-to-fuel value chain

  • Exploring carbon sequestration opportunities at production sites

  • Promoting the use of higher ethanol blends like E15 and E85


4️⃣ 7. Cardinal Ethanol, LLC

Headquarters: Union City, Indiana, USA
Key Offering: Fuel Ethanol, Distillers Grains, Corn Oil

Cardinal Ethanol is a prominent farmer-owned ethanol producer in the eastern Corn Belt. The company exemplifies the success of the cooperative model, directly benefiting local corn growers and contributing to rural economic development.

Sustainability & Innovation Initiatives:

  • Implementation of energy-efficient technologies to reduce natural gas consumption

  • Focus on local economic impact and community engagement

  • Ongoing process improvements to enhance yield and reduce emissions


3️⃣ 8. Henan Tianguan Group Co., Ltd.

Headquarters: Nanyang, Henan, China
Key Offering: Fuel Ethanol, Edible Alcohol, Biochemical Products

Henan Tianguan Group is one of China’s leading biofuel enterprises, playing a crucial role in the country’s mandate to blend ethanol into its gasoline supply. The company utilizes domestic corn and other feedstocks to support China’s energy security and pollution reduction goals.

Sustainability & Innovation Initiatives:

  • Expansion of production capacity to meet national E10 blending targets

  • Research into cellulosic ethanol and other advanced biofuel pathways

  • Integration of biofuel production with other biochemical outputs


2️⃣ 9. China National Petroleum Corporation (CNPC)

Headquarters: Beijing, China
Key Offering: Fuel Ethanol, Petroleum Products

As one of China’s largest state-owned oil and gas corporations, CNPC is a key participant in the nation’s biofuel sector. The company produces corn-based ethanol to comply with government blending policies, integrating biofuels into its vast fuel distribution network.

Sustainability & Innovation Initiatives:

  • Strategic alignment with China’s national carbon peaking and neutrality goals

  • Investment in biofuel plants as part of a broader energy diversification strategy

  • Exploration of co-processing biofuels in traditional refineries


1️⃣ 10. COFCO Corporation

Headquarters: Beijing, China
Key Offering: Ethanol, Starch, Sweeteners

COFCO, China’s largest food processing, and trading company, is also a major producer of corn-based ethanol. Leveraging its immense agricultural sourcing capabilities, COFCO produces ethanol for fuel and industrial uses, contributing significantly to the country’s renewable energy mix.

Sustainability & Innovation Initiatives:

  • Utilization of its integrated agricultural supply chain for efficient feedstock sourcing

  • Focus on producing high-value co-products from the ethanol production process

  • Commitment to supporting national energy and environmental policies

Get Full Report Here: Corn-Based Ethanol Market – View in Detailed Research Report


🌍 Outlook: The Future of Corn-Based Ethanol Is Sustainable and Integrated

The corn-based ethanol market is at a pivotal juncture. While it remains a vital component of the current renewable fuel landscape, the industry is actively evolving to address challenges related to carbon intensity and land use. The focus is shifting toward greater sustainability, technological innovation, and deeper integration into the bioeconomy.

📈 Key Trends Shaping the Market:

  • Accelerated adoption of carbon capture, utilization, and storage (CCUS) to produce low-carbon ethanol

  • Policy support for higher ethanol blends (E15, E85) in key markets like the U.S. and Canada

  • Growing interest in corn ethanol as a feedstock for sustainable aviation fuel (SAF) production

  • Continuous process innovations to improve yields, reduce energy consumption, and create higher-value co-products

Get Full Report Here: Corn-Based Ethanol Market – View in Detailed Research Report

The companies profiled above are not only powering millions of vehicles with renewable fuel—they are pioneering the advanced biorefining technologies essential for a lower-carbon future.