The Global Polycrystalline Black Phosphorus Market was valued at USD 45.2 Million in 2023 and is projected to reach USD 112.8 Million by 2030, growing at a Compound Annual Growth Rate (CAGR) of 14.7% during the forecast period (2024–2030). This expansion is driven by surging demand across semiconductor manufacturing, energy storage systems, and advanced photonic applications where this 2D material outperforms conventional silicon and graphene alternatives.

As nanotechnology advances create new possibilities in material science, polycrystalline black phosphorus has emerged as a revolutionary semiconductor with anisotropic electrical properties and tunable bandgaps. This analysis profiles the Top 10 Companies in the Global Polycrystalline Black Phosphorus Market—industry pioneers transforming everything from flexible electronics to quantum computing through material innovation.

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🔟 1. ACS Material

Headquarters: Medford, Massachusetts, USA
Key Offering: Research-grade black phosphorus (4N-6N purity), customized formulations

A leading nanomaterials specialist, ACS Material supplies high-purity polycrystalline black phosphorus to laboratories and industrial partners worldwide. The company maintains ISO 9001-certified production facilities with strict quality control protocols.

Material Innovation:

• Patented vapor-phase deposition techniques for large-area synthesis
• Surface passivation technologies improving environmental stability
• Custom doping services for tailored electronic properties

Download FREE Sample Report: Global Polycrystalline Black Phosphorus Market – View in Detailed Research Report

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9️⃣ 2. 2D Semiconductors

Headquarters: Scotts Valley, California, USA
Key Offering: Mono/few-layer black phosphorus flakes (1μm-100μm)

This advanced materials company focuses exclusively on 2D semiconductor development, supplying black phosphorus for cutting-edge transistor and sensor applications requiring precise thickness control.

Material Innovation:

• Proprietary mechanical exfoliation techniques
• Atomic layer deposition compatibility solutions
• Integration support for device prototyping

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8️⃣ 3. Mophos

Headquarters: Austin, Texas, USA
Key Offering: Commercial-scale black phosphorus production

Mophos has developed scalable synthesis methods that bring black phosphorus from research laboratories to industrial applications, offering both small research quantities and bulk commercial supply.

Material Innovation:

• High-pressure synthesis technology
• Cost-effective production at >100g batches
• Custom particle size distributions

Download FREE Sample Report: Global Polycrystalline Black Phosphorus Market – View in Detailed Research Report

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7️⃣ 4. 6Carbon Technology

Headquarters: Suzhou, China
Key Offering: 5N+ purity black phosphorus for electronics

As China’s leading black phosphorus producer, 6Carbon Technology supplies the booming Asian semiconductor industry with material meeting strict purity requirements for advanced node manufacturing.

Material Innovation:

• Proprietary zone refining techniques
• Defect density < 10⁸ cm^-2
• Oxidation-resistant packaging solutions

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6️⃣ 5. American Elements

Headquarters: Los Angeles, California, USA
Key Offering: Ultra-high purity black phosphorus (up to 99.999%)

American Elements provides black phosphorus across the purity spectrum, from industrial grades to research-grade materials certified for sensitive semiconductor applications.

Material Innovation:

• GMP-compliant production facilities
• Custom alloying and composite development
• Nano-formulations for specialty applications

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5️⃣ 6. HQ Graphene

Headquarters: Groningen, Netherlands
Key Offering: Black phosphorus films on various substrates

Specializing in 2D material integration, HQ Graphene provides pre-deposited black phosphorus films optimized for research institutions and device manufacturers across Europe.

Material Innovation:

• Substrate transfer expertise (SiO₂, PET, etc.)
• Wafer-scale deposition capabilities
• Characterization services including Raman mapping

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4️⃣ 7. Manchester Nanomaterials

Headquarters: Manchester, UK
Key Offering: Research samples with extensive characterization data

Founded by University of Manchester researchers, this company provides fully characterized black phosphorus samples accompanied by comprehensive spectral and electronic property data.

Material Innovation:

• Advanced AFM/STEM characterization
• Electronic structure analysis reports
• Collaborative research programs

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3️⃣ 8. WEISTRON

Headquarters: New Taipei City, Taiwan
Key Offering: Battery-grade black phosphorus composites

WEISTRON develops enhanced black phosphorus formulations specifically for next-generation lithium-ion batteries and supercapacitors, focusing on energy storage applications.

Material Innovation:

• Conductivity-enhanced composites
• Electrochemical performance testing
• Industrial-scale masterbatch production

Download FREE Sample Report: Global Polycrystalline Black Phosphorus Market – View in Detailed Research Report

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2️⃣ 9. Smart-elements

Headquarters: Vienna, Austria
Key Offering: Single-crystal black phosphorus

Smart-elements specializes in high-quality single-crystal black phosphorus for fundamental research in physics, chemistry, and materials science laboratories.

Material Innovation:

• Crystal growth optimization
• Anisotropic property characterization
• Surface functionalization services

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1️⃣ 10. Taizhou Sunano Energy

Headquarters: Taizhou, China
Key Offering: Black phosphorus for optoelectronic applications

This Chinese innovator develops specialized black phosphorus formulations for photodetectors, solar cells, and other light-sensitive semiconductor devices.

Material Innovation:

• Tunable bandgap formulations
• Large-area deposition technologies
• Quantum efficiency enhancement

Get Full Report Here: Global Polycrystalline Black Phosphorus Market – View in Detailed Research Report

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🌍 Outlook: Black Phosphorus Shaping Next-Gen Technologies

The polycrystalline black phosphorus market stands at an inflection point, transitioning from academic research to commercial adoption across multiple high-tech industries. Its unique combination of tunable bandgap, high carrier mobility, and anisotropic properties makes it ideal for specialized applications where silicon reaches its limits.

📈 Emerging Market Trends:

• Adoption in flexible/wearable electronics requiring bendable semiconductors
• Integration into advanced photonic and optoelectronic devices
• Development of protective coatings enabling industrial applications
• Growing investment from Asian semiconductor supply chains

Get Full Report Here: Global Polycrystalline Black Phosphorus Market – View in Detailed Research Report

The companies featured above represent the vanguard of black phosphorus commercialization—transforming this once-laboratory curiosity into the foundation for tomorrow’s electronic and energy technologies.